Issue 1, 1990
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reaction of [Rh(η4-cot)(η-C5H5)](cot = cyclo-octatetraene) with [Fe{P(OMe)3}(NO)2(η3-CH2 CHCH2)]+: allylic alkylation of a cyclopentadienyl ring

Neil G. Connelly  and  Mark Gilbert  

Abstract

The reaction of [Rh(η4-cot)(η-C5H5)](cot = cyclo-octatetraene) with [Fe{P(OMe)3}(NO)2-(η3-CH2CHCH2)][PF6] gives [Rh(η2,η3-C8H9)(η-C5H4R)][PF6](R = CH2CH[double bond, length as m-dash]CH2)via allyl addition to the cyclopentadienyl ring and proton migration to the co-ordinated cot.

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Article information

DOI
https://doi.org/10.1039/DT9900000373
Article type
Paper

J. Chem. Soc., Dalton Trans., 1990, 373-374

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Reaction of [Rh(η4-cot)(η-C5H5)](cot = cyclo-octatetraene) with [Fe{P(OMe)3}(NO)2(η3-CH2 CHCH2)]+: allylic alkylation of a cyclopentadienyl ring

N. G. Connelly and M. Gilbert, J. Chem. Soc., Dalton Trans., 1990, 373 DOI: 10.1039/DT9900000373

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