The tetrahedral heterobimetallic cluster (C5H5)NiRu3H3(CO)9 produces a finely divided Ni–Ru alloy powder by chemically induced decomposition in tetrahydrofuran and an alumina-supported bimetallic catalyst, active in ammonia synthesis, by thermal treatment under flowing dihydrogen.
G. Predieri, P. Moggi, S. Papadopulos, A. Armigliato, S. Bigi and E. Sappa, J. Chem. Soc., Chem. Commun., 1990, 1736 DOI: 10.1039/C39900001736
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