Issue 23, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Cleavage of C[double bond, length half m-dash]S multiple bonds by unsaturated cobalt centres: crystal structure of [(C5H5)[graphic ommitted]}(CNPh)]

Ian R. Beaumont,   Michael J. Begley,   Simon Harrison  and  Anthony H. Wright  

Abstract

Multiple C[double bond, length half m-dash]S bond cleavage takes place at ambient temperatures when isothiocyanates react with [(C5H5)Co(C2H4)2] giving five-membered metallacyclic complexes such as the structurally characterised complex [(C5H5)Co{C(NPh)NPhC(S)S}(CNPh)].

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Article information

DOI
https://doi.org/10.1039/C39900001713
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1713-1715

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Cleavage of C[double bond, length half m-dash]S multiple bonds by unsaturated cobalt centres: crystal structure of [(C5H5)[graphic ommitted]}(CNPh)]

I. R. Beaumont, M. J. Begley, S. Harrison and A. H. Wright, J. Chem. Soc., Chem. Commun., 1990, 1713 DOI: 10.1039/C39900001713

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