Issue 23, 1990

Thermal rearrangement of ethyl 5-nitro-4-phenyl-2-oxa-3-azabicyclo[3.1.0]hex-3-ene-1-carboxylate into a quinoxaline system

Abstract

The title compound 2 is found to undergo thermal isomerization into the quinoxaline derivative 3, as shown by a crystal structure determination of the latter; a mechanistic rationale for this unusual rearrangement is suggested.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1675-1676

Thermal rearrangement of ethyl 5-nitro-4-phenyl-2-oxa-3-azabicyclo[3.1.0]hex-3-ene-1-carboxylate into a quinoxaline system

R. Nesi, D. Giomi, S. Papaleo, P. Dapporto and P. Paoli, J. Chem. Soc., Chem. Commun., 1990, 1675 DOI: 10.1039/C39900001675

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