A simple and efficient method for the remote (1,4- and/or 1,5-) stereocontrol was realized by utilizing an intramolecular carbonyl reduction with ThexBH2(Thex = 1,1,2-trimethylpropyl).
T. Harada, Y. Matsuda, S. Imanaka and A. Oku, J. Chem. Soc., Chem. Commun., 1990, 1641 DOI: 10.1039/C39900001641
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