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Issue 22, 1990
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A novel zwitterionic ortho-metallated ruthenium(II) phenolate

Abstract

Decarbonylative metallation of the dialdehyde 2b by [Ru(PPh3)3Cl2] affords the unusual complex [Ru(MeL)(CO)(PPh3)2(Cl)]4 which has been characterised by X-ray crystallography and in which the RuIIP2C2ClO coordination unit bears a single net negative charge; the Ru(MeL)(3, R = Me) fragment incorporates a four-membered C,O-chelated phenolato function with a neighbouring monoprotonated azomethine moiety.

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Article information


J. Chem. Soc., Chem. Commun., 1990, 1626-1627
Article type
Paper

A novel zwitterionic ortho-metallated ruthenium(II) phenolate

N. Bag, S. B. Choudhury, G. K. Lahiri and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1990, 1626
DOI: 10.1039/C39900001626

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