Issue 22, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel two-coordinate germanium(II) arylamides: Ge(NHAr)2, ArN[Ge(NHAr)]2(µ-NAr) and [Ge(µ-NAr)]2 2, and the X-ray structures of 2 and Sn(NHAr)2(Ar = C6H2But3-2,4,6)

Peter B. Hitchcock,   Michael F. Lappert  and  Andrew J. Thorne  

Abstract

Depending on reaction conditions, treatment of GeCl2(1,4-dioxane) with [Li(µ-NHAr)(L)]2(L = OEt2 or OC4H8) yields Ge(NHAr)21 or the first binuclear group 14 element(II) amides [Ge(µ-NAr)]22 or ArN[Ge(NHAr)]2(µ-NAr)3; X-ray structural data are presented on the tin analogue of 1 and on the germetane 2.

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Article information

DOI
https://doi.org/10.1039/C39900001587
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1587-1589

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Novel two-coordinate germanium(II) arylamides: Ge(NHAr)2, ArN[Ge(NHAr)]2(µ-NAr) and [Ge(µ-NAr)]2 2, and the X-ray structures of 2 and Sn(NHAr)2(Ar = C6H2But3-2,4,6)

P. B. Hitchcock, M. F. Lappert and A. J. Thorne, J. Chem. Soc., Chem. Commun., 1990, 1587 DOI: 10.1039/C39900001587

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