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Issue 21, 1990
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Intramolecular cyclopropane formation by insertion of an iron–carbene species into a C–H bond

Abstract

The bimetallic carbene complex [Cp*Fe(CO)2(µ-η16-CHCMe2C6H5)FeCp][PF6]22, spectroscopically observed by 1H NMR at –80°C, undergoes intramolecular C–H insertion to give [CpFe(η6-1-phenyl-1-methylcyclopropane)][PF6]3.

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Article information


J. Chem. Soc., Chem. Commun., 1990, 1550-1552
Article type
Paper

Intramolecular cyclopropane formation by insertion of an iron–carbene species into a C–H bond

V. Guerchais and S. Sinbandhit, J. Chem. Soc., Chem. Commun., 1990, 1550
DOI: 10.1039/C39900001550

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