L-[2,4,5,6,7-2H5]Tryptophan has been incorporated into roquefortine and aszonalenin, by Penicillium roqueforti and by Aspergillus zonatus respectively, with retention of five deuterium atoms; the 5a-hydrogen of each of these metabolites is derived from the 2-hydrogen of tryptophan, contrary to an earlier report.
B. Bhat, D. M. Harrison and H. M. Lamont, J. Chem. Soc., Chem. Commun., 1990, 1518 DOI: 10.1039/C39900001518
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