The co-thermolysis of [(Cp)Cr(CO)3]2(Cp =η5-C5H5) with P4 forms [(Cp)Cr(CO)2]5P10, a new paramagnetic structure with a P10 core, which represents the first example of polycyclic phosphorus-to-metal coordination.
L. Y. Goh, R. C. S. Wong and E. Sinn, J. Chem. Soc., Chem. Commun., 1990, 1484 DOI: 10.1039/C39900001484
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