Issue 21, 1990

Structure sensitivity for ethene dimerization, homologation and metathesis on SiO2-supported catalysts derived from Mo(NMe2)4 and Mo2(NMe2)6

Abstract

The SiO2 grafted dimer precursor (Me2N)3Mo[triple bond, length half m-dash]Mo(NMe2)3 specifically exhibited catalytic activity for ethene dimerization, whereas the monomer Mo(NMe2)4 derived catalyst showed high activity for ethene homologation, but was inactive for ethene dimerization.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1477-1478

Structure sensitivity for ethene dimerization, homologation and metathesis on SiO2-supported catalysts derived from Mo(NMe2)4 and Mo2(NMe2)6

Q. Zhuang, K. Tanaka and M. Ichikawa, J. Chem. Soc., Chem. Commun., 1990, 1477 DOI: 10.1039/C39900001477

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