Photoreaction of the title compound Phl+–C(RFSO2)2 which was synthesised by the reaction of bis(perfluoroalkanesulphonyl) methane with diacetoxyiodobenzene, with alkene, methanol, bromine and benzene gave corresponding addition or insertion products, via the bis(perfluoroalkanesulphonyl) carbene, (RFSO2)2C: intermediate.
S. Zhu and Q. Chen, J. Chem. Soc., Chem. Commun., 1990, 1459 DOI: 10.1039/C39900001459
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