The quantitative formation of MeCNl+ from MeCN and I3+ in SO2 and the back reaction (MeCNl++ I2 gives MeCN + I3+) are discussed on the basis of the HSAB principle.
P. K. Gowik and T. M. Klapötke, J. Chem. Soc., Chem. Commun., 1990, 1433 DOI: 10.1039/C39900001433
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