Intermolecular reaction of an organo-radical with thioester gives the sulphide, which is formed by the sulphur centred substitution of acyl groups with a nucleophilic organo-radical, but no displacement of S-alkyl groups with the organo-radical takes place.
M. Tada, T. Uetake and M. Matsumoto, J. Chem. Soc., Chem. Commun., 1990, 1408 DOI: 10.1039/C39900001408
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