Details of the rearrangement of the η2-vinyl complex [[graphic omitted]Me(Ph)}{P(OMe)3}2(η-C5H5)]1 to the η3-allyl species [Mo{η3-CH2C(Ph)CH(Ph)}{P(OMe)3}2(η-C5H5)]2a, 2b, and of [[graphic omitted]H(Ph)}(CO)(PMe2Ph)(η-C5H5)]3 into [Mo{![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CCHPh2}(CO)(PMe2Ph)(η-C5H5)]4, are described together with a crystal structure determination of 2b and possible mechanistic pathways.
W. Clegg, M. Green, C. A. Hall, D. C. R. Hockless, N. C. Norman and C. M. Woolhouse, J. Chem. Soc., Chem. Commun., 1990, 1330 DOI: 10.1039/C39900001330
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