SCHEDULED MAINTENANCE
The first example of a dithiarsolidinium cation has a novel dimeric structure, while the spirocyclic bis(ethanediyldithio)phosphonium cation has been isolated from attempts to obtain the corresponding dithiaphospholidinium cation, both observations illustrating the importance of supplemental stabilisation for low-co-ordinate group 15 elements.
N. Burford, B. W. Royan, J. M. Whalen, J. F. Richardson and R. D. Rogers, J. Chem. Soc., Chem. Commun., 1990, 1273 DOI: 10.1039/C39900001273
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