Examination of the reaction of [Cp2Zr(n-octyl)2](2) with D2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH–n-hexyl or styrene in the presence of PMe3 by NMR spectroscopy rules out dissociative mechanisms for the conversion of (2) into alkene–ZrCp2–PMe3 complexes involving free ZrCp2 and supports non-dissociative mechanisms (Cp = cyclopentadienyl).
E. Negishi, D. R. Swanson and T. Takahashi, J. Chem. Soc., Chem. Commun., 1990, 1254 DOI: 10.1039/C39900001254
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