Intramolecular reductive coupling of nitrite with alkene units in the presence of zirconocene prepared from (C5H5)2ZrCl2 and BuLi gives cyclic ketones; the intermediary metallacycle prepared from the 2-cyano-N-allylaniline derivative is very reactive and provides various quinoline derivatives by treatment with electrophiles and other reagents.
M. Mori, N. Uesaka and M. Shibasaki, J. Chem. Soc., Chem. Commun., 1990, 1222 DOI: 10.1039/C39900001222
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