A dramatic change in the sulphur–nitrogen selectivity of the SCN substitution of t-butyl bromide was observed, in addition to a dramatic increase in reaction rate, by simply supporting various alkaline earth metal thiocyanates on various inorganic solids.
T. Kimura, M. Fujita and T. Ando, J. Chem. Soc., Chem. Commun., 1990, 1213 DOI: 10.1039/C39900001213
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