Direct oxidative addition of thionyl chloride (SOCl2) to a nickel(0) complex is an unprecedented procedure for the preparation of sulphur monoxide complexes of the type [Ni2(µ-SO)(PPh2CH2PPh2)2Cl2] in which the µ-SO group was found by an X-ray structural study to be tilted with respect to the Ni–Ni vector.
J. K. Gong, P. E. Fanwick and C. P. Kubiak, J. Chem. Soc., Chem. Commun., 1990, 1190 DOI: 10.1039/C39900001190
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