Feeding experiments with labelled trichodiene (1) in Fusarium culmorum cultures have resulted in the isolation of a new metabolite, Isotrichodiol (9), that is subsequently transformed into trichothecene toxins, and thus represents the first demonstrated post-trichodiene intermediate in the biosynthetic pathway to trichothecenes.
A. R. Hesketh, L. Gledhill, D. C. Marsh, B. W. Bycroft, P. M. Dewick and J. Gilbert, J. Chem. Soc., Chem. Commun., 1990, 1184 DOI: 10.1039/C39900001184
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