SCHEDULED MAINTENANCE
Ab initio quantum mechanical calculations using split valence plus polarization function (MIDI*) basis sets including electron correlation correction (MP2) show that the bridge structure, where the metal atom interacts with both ends of the SiO molecule, is a stable adduct and the calculated electronic structure is in better agreement with recent ESR observations than the linear structure proposed earlier.
J. S. Tse, J. Chem. Soc., Chem. Commun., 1990, 1179 DOI: 10.1039/C39900001179
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