Issue 16, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Selective carbonylation of propane in superacid media via hydride abstraction by the chlorocarbocations: CCl3+ and CHCl2+

Jean-Christophe Culmann,   Michel Simon  and  Jean Sommer  

Abstract

Carbonylation of propane in HF–SbF5(5 : 1 molar ratio) superacid in the presence of carbon tetrachloride (or chloroform) at –30 °C yields exclusively the isobutyryl ion (isopropyloxocarbenium ion), analysis of the gaseous fluorocarbons generated as side products showing both hydride abstraction by CCl3+(or CHCl2+) and Cl/F exchange on the tri- and di-chloromethane formed; in the absence of CCl4(or CHCl3) no reaction takes place under the same experimental conditions.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39900001098
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1098-1100

Permissions

Request permissions

Selective carbonylation of propane in superacid media via hydride abstraction by the chlorocarbocations: CCl3+ and CHCl2+

J. Culmann, M. Simon and J. Sommer, J. Chem. Soc., Chem. Commun., 1990, 1098 DOI: 10.1039/C39900001098

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements