The Intramolecular addition of a titanocene vinylidene complex formed by dechlorodimethylalumination of a 1-dimethylalumino-1-bis(η5-cyclopentadienyl)chlorotitano-alkene to an unactivated alkene or alkyne affords bicyclic titanacyclobutanes or titanacyclobutenes.
R. D. Dennehy and R. J. Whitby, J. Chem. Soc., Chem. Commun., 1990, 1060 DOI: 10.1039/C39900001060
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