Issue 15, 1990

Iridium(I), -(III), and -(V) complexes of an O-donor ligand in alkyne hydrosilylation

Abstract

The O-donor ligand C(Ph2PO)3(triso) stabilises iridium-(I), -(III), and -(V) species such as [(triso)IrH2(SiMePh2)2]; the complexes catalyse the net anti-addition of silanes to alkynes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1056-1057

Iridium(I), -(III), and -(V) complexes of an O-donor ligand in alkyne hydrosilylation

R. S. Tanke and R. H. Crabtree, J. Chem. Soc., Chem. Commun., 1990, 1056 DOI: 10.1039/C39900001056

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