Synthesis and properties of binuclear [LTiCl2(µ-O)TiCl2L]n+(n= 0, 1, 2; L = 1,4,7-trimethyl-1,4,7-triazacyclononane) complexes. The crystal structure of the mixed valence compound [L2Ti2Cl4(µ-O)]Cl·2H2O
Abstract
Three linearly µ-oxo bridged binuclear complexes [L2Ti2Cl4(µ-O)]n+(n = 0,1,2) have been synthesized and the mixed valence complex [L2Ti2Cl4(µ-O)]Cl·2H2O has been characterized by X-ray crystallography (L = 1,4,7-trimethyl-1,4,7-triazacyclononane).