The observation of an NO2–˙ radical intermediate in the pulse-radiolytic reduction of spinach plastocyanin PCuI, NO2-modified at Tyr83, but not in the case of the PCuII derivative, is consistent with a rapid NO2–˙ CuII Intramolecular electron-transfer process with K>107 S–1.
K. Govindaraju, G. A. Salmon, N. P. Tomkinson and A. G. Sykes, J. Chem. Soc., Chem. Commun., 1990, 1003 DOI: 10.1039/C39900001003
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