Issue 14, 1990

The flexibility of bridging phosphinoyl ligands: new classes of triplatinum(II) and diplatinum(I) complexes

Abstract

The reactions of [Pt2(µ-OH)2(POPh2)2(PR3)2] with (i) HBF4 or HPF6 to give the tiplatinum complexes [Pt33-OH)(µ-OPPh2)3(PR3)3]2+(2) and (ii) alcohols to give the diplatinum complexes [Pt2(µ-OPPh2)2(PR3)2](4) are described; the X-ray crystal structures of (2a) and (4a) show the OPPh2 ligand is capable of spanning Pt ⋯ Pt distances of 2.55 to 3.71 Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 980-982

The flexibility of bridging phosphinoyl ligands: new classes of triplatinum(II) and diplatinum(I) complexes

N. W. Alcock, P. Bergamini, T. M. Gomes-Carniero, R. D. Jackson, J. Nicholls, A. G. Orpen, P. G. Pringle, S. Sostero and O. Traverso, J. Chem. Soc., Chem. Commun., 1990, 980 DOI: 10.1039/C39900000980

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