The linear S![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
PS+ form of the recently studied PS2+ ion lies below the triangular one in energy; the calculated frequencies for the trithiometaphosphate anion, PS3–(D3h) support its experimental identification in high-temperature melts and in (AsPh4)PS3.
P. Pyykkö, J. Chem. Soc., Chem. Commun., 1990, 933 DOI: 10.1039/C39900000933
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