Issue 13, 1990

Stereodynamic protection of a carbonyl group by two benzene rings against interaction with a triplet n→π* quencher in the photochemical reaction of 5,6,7,12,13,14-hexahydro-6,13-methanodibenzo[a,f]cyclodecen-15-one

Abstract

In the photolysis of the flexible 5,6,7,12,13,14-hexahydro-6,13-methanodibenzo[a,f]cyclodecen-15-one (1), the two annulated benzene rings protected the carbonyl group against interaction with a triplet quencher such as naphthalene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 930-931

Stereodynamic protection of a carbonyl group by two benzene rings against interaction with a triplet n→π* quencher in the photochemical reaction of 5,6,7,12,13,14-hexahydro-6,13-methanodibenzo[a,f]cyclodecen-15-one

S. Mataka, S. T. Lee and M. Tashiro, J. Chem. Soc., Chem. Commun., 1990, 930 DOI: 10.1039/C39900000930

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