Sulphamide promotes a net intramolecular cyclocondensation of triphosphate to trimetaphosphate in dilute aqueous solution at pH 8–10, as well as the formation of amidophosphates from diphosphate and triphosphate; the relatively saturated character of the reactive S–N bond of sulphamide contrasts that of previously examined aqueous-phase phosphate condensing agents.
D. R. Gard and E. J. Griffith, J. Chem. Soc., Chem. Commun., 1990, 881 DOI: 10.1039/C39900000881
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