The introduction of a ferrocenyl moiety at the 17α-position of estradiol brings about a dramatic change in the behaviour of the hormone at the receptor binding site since an irreversible binding takes place; this unusual reactivity may help to elucidate the steroid's mode of action.
A. Vessiēres, C. Vaillant, M. Gruselle, D. Vichard and G. Jaouen, J. Chem. Soc., Chem. Commun., 1990, 837 DOI: 10.1039/C39900000837
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