FTIR-microscopy has been used in situ to characterise catalyst surfaces; with CO on graphite-supported Pt during chemisorption and oxidation it reveals surface heterogeneity and may suggest that the more reactive bridge-bound CO is predominantly found at the outer edge of CO islands on the surface.
V. A. Self and P. A. Sermon, J. Chem. Soc., Chem. Commun., 1990, 834 DOI: 10.1039/C39900000834
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