Issue 11, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel five-co-ordinate osmium–oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)2C(Me)2NH}{NH2C(Me)2C(Me)2NH}]ClO4

Chi-Ming Che,   Michael Hon-Wah Lam,   Ru-Ji Wang  and  Thomas C. W. Mak  

Abstract

The six-co-ordinate trans-[Os(L)2(O)2]2+[L = NH2C(Me)2C(Me)2NH2] and five-co-ordinate [OsO{NHC(Me)2C(Me)2NH}{NH2C(Me)2C(Me)2NH}]+ complexes are in equilibrium in solution; the X-ray structure of the five-co-ordinate square pyramidal OsVI-oxo complex has been determined with a measured Os[double bond, length half m-dash]O distance of 1.72(2)Å.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39900000820
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 820-821

Permissions

Request permissions

Novel five-co-ordinate osmium–oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)2C(Me)2NH}{NH2C(Me)2C(Me)2NH}]ClO4

C. Che, M. H. Lam, R. Wang and T. C. W. Mak, J. Chem. Soc., Chem. Commun., 1990, 820 DOI: 10.1039/C39900000820

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements