Photolysis of 1,5-, 1,6-, 1,8-, and 2,7-diazidonaphthalenes (1) results in ring expansion of both benzene rings to give the corresponding novel azepinoazepines (3)via the azidobenzazepines (2).
H. Sawanishi, H. Muramatsu and T. Tsuchiya, J. Chem. Soc., Chem. Commun., 1990, 628 DOI: 10.1039/C39900000628
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