Following γ-irradiation of cyclo-octatetraene in Freon solvents at 77 K, a single central feature was observed by ESR spectroscopy, from the parent radical cation; after bleaching with visible light, this changed to a triplet (36.4 G) of quintets (7.8 G) pattern, assigned to the rearranged cation (IV).
C. J. Rhodes, J. Chem. Soc., Chem. Commun., 1990, 592 DOI: 10.1039/C39900000592
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