Issue 7, 1990

Model compounds for the active sites of oxo-transfer molybdoenzymes. Synthesis, structural characterization, and electrochemical properties of [NH4]2[MoO2{O2CC(S)Ph2}2]

Abstract

[NH4]2[MoO2{O2CC(S)Ph2}2]middot;2H2O has been prepared and its crystal structure solved, providing the first example of a co-ordinatively saturated molybdenum complex which reacts readily and reversibly with organophosphines at room temperature in water or methanol; its variable-temperature 13C{1H} NMR spectra and electrochemical properties are presented.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 531-533

Model compounds for the active sites of oxo-transfer molybdoenzymes. Synthesis, structural characterization, and electrochemical properties of [NH4]2[MoO2{O2CC(S)Ph2}2]

P. Palanca, T. Picher, V. Sanz, P. Gömez-Romero, E. Llopis, A. Domenech and A. Cervilla, J. Chem. Soc., Chem. Commun., 1990, 531 DOI: 10.1039/C39900000531

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements