The hexa Schiff base macrocycle formed by condensation of three molecules of 2, 6-diformyl-4-methylphenol with three molecules of 2, 6-bis(aminomethyl)-4-methylphenol binds six copper(II) ions in a cyclohexane boat arrangement with two µ2-hydroxo groups (O ⋯ O separation 3.32 Å) occupying the central cavity.
B. F. Hoskins, R. Robson and P. Smith, J. Chem. Soc., Chem. Commun., 1990, 488 DOI: 10.1039/C39900000488
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