Issue 5, 1990

Syntheses of anomeric glucopyranosylidene diazides

Abstract

Protected glucopyranosylidene diazides have been obtained in good yields by two routes which involve nucleophilic substitutions at the anomeric polsition of either 2,3,4,6-tetra-O-acetyl-1-bromo-β-D-glucopyranosyl chloride or 2,3,4,6-tetra-O-benzyl-D-glucono-1,5-lactone, in the presence of silver azide or trimethylsilyl azide, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 431-432

Syntheses of anomeric glucopyranosylidene diazides

J.-P. Praly, Z. E. Kharraf and G. Descotes, J. Chem. Soc., Chem. Commun., 1990, 431 DOI: 10.1039/C39900000431

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