SCHEDULED MAINTENANCE
Different extents of decomposition for the cis and trans isomers of 4,5-epoxycyclo-octyl hydroperoxide coupled with the formation of oxygen (identified by Raman spectroscopy) and bicyclic ethers suggest a mechanism involving the heterolytic formation of protonated alkyl hydrotrioxides by nucleophilic attack of hydroperoxide on gem-dialkylperoxonium ions.
S. P. Best, A. J. Bloodworth and M. D. Spencer, J. Chem. Soc., Chem. Commun., 1990, 416 DOI: 10.1039/C39900000416
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