The 15N nuclear polarisation in the dinitro and vitro-nitrito products from the addition of nitrogen dioxide to 2-ethylbut-1-ene is consistent with the separate addition of two nitrogen dioxide radicals.
J. L. Powell, J. H. Ridd and J. P. B. Sandall, J. Chem. Soc., Chem. Commun., 1990, 402 DOI: 10.1039/C39900000402
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