SCHEDULED MAINTENANCE
The title compounds have been prepared in high yields by the reactions of Na[cpM(CO)3] with [Os3(CO)12Cl(SnCl3)](cp =η5-C5H5) and the tungsten compound has been shown, by X-ray crystallography, to contain a pentametallic chain held together only by metal–metal bonds.
D. B. Firfiray, A. Irving and J. R. Moss, J. Chem. Soc., Chem. Commun., 1990, 377 DOI: 10.1039/C39900000377
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