Issue 4, 1990

Kinetic isotope effects involving deuteriated aniline nucleophiles

Abstract

Primary and secondary α-deuterium kinetic isotope effects are observed with deuteriated aniline nucleophiles in the SN2 reactions of 1-phenylethyl and benzyl benzenesulphonates, providing evidence in support of the four centre transition state mechanism for the former reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 335-336

Kinetic isotope effects involving deuteriated aniline nucleophiles

I. Lee, H. J. Koh, B. Lee and H. W. Lee, J. Chem. Soc., Chem. Commun., 1990, 335 DOI: 10.1039/C39900000335

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