Rate and activation parameters for ligand substitution reactions on a severely sterically hindered Pd(II) complex indicate that steric crowding controls the nucleophilicity scale but not the nature of the substitution mechanism.
H. Krüger and R. van Eldik, J. Chem. Soc., Chem. Commun., 1990, 330 DOI: 10.1039/C39900000330
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