Heating (vinylketene)tricarbonyliron(0) complexes with isonitriles at 80 °C gives (vinylketenimine)tricarbonyliron(0) complexes via intermediate (vinylketene)dicarbonylisonitrileiron(0) complexes.
C. J. Richards and S. E. Thomas, J. Chem. Soc., Chem. Commun., 1990, 307 DOI: 10.1039/C39900000307
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