Issue 4, 1990

Molecular precursors of bismuth oxide. Synthesis and structure of [Bi22-OC2H4OMe)4(OC2H4OMe)2]∞, a one-dimensional ribbon-like chain

Abstract

Compounds [Bi(OBut)3]∞ and [Bi22-OC2H4OMe)4(OC2H4OMe)2]∞ have been obtained by metathesis reactions between bismuth halides and the appropriate alkali alkoxides; X-ray structure analysis shows a one-dimensional extended ‘skew’ chain structure based on dimeric asymmetric Bi2(OC2H4OMe)6 units in which the metal displays a pyramidal tetragonal surrounding, with a small number of additional neighbours.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 301-302

Molecular precursors of bismuth oxide. Synthesis and structure of [Bi22-OC2H4OMe)4(OC2H4OMe)2]∞, a one-dimensional ribbon-like chain

M. Massiani, R. Papiernik, L. G. Hubert-Pfalzgraf and J. Daran, J. Chem. Soc., Chem. Commun., 1990, 301 DOI: 10.1039/C39900000301

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