Issue 3, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Room temperature activation of an aliphatic C–H bond: synthesis and structure of the ruthenium clusters [(µ2-H)Ru3(CO)8(µ3-S)(η2-CH2CMe2NHCNHBut)] and [(µ2-H)Ru3(CO)9{µ3-S-Ru(CO)3(η2-CH2CMe2NHCNHBut)}]

Ulf Bodensieck,   Helen Stoeckli-Evans  and  Georg Süss-Fink  

Abstract

The thiourea derivative (Me3CNH)2CS reacts with [Ru3(CO)12] in tetrahydrofuran with C[double bond, length half m-dash]S bond cleavage and oxidative addition of the non-activated C–H bond of a peripheral methyl group; the reaction proceeds in the dark at room temperature.

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Article information

DOI
https://doi.org/10.1039/C39900000267
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 267-268

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Room temperature activation of an aliphatic C–H bond: synthesis and structure of the ruthenium clusters [(µ2-H)Ru3(CO)8(µ3-S)(η2-CH2CMe2NHCNHBut)] and [(µ2-H)Ru3(CO)9{µ3-S-Ru(CO)3(η2-CH2CMe2NHCNHBut)}]

U. Bodensieck, H. Stoeckli-Evans and G. Süss-Fink, J. Chem. Soc., Chem. Commun., 1990, 267 DOI: 10.1039/C39900000267

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