Electrophilically catalysed cleavage of the N–O bond of N,N-dimethoxyamine results in the formation of singlet N-methoxynitrenium ion, which aminates soft nucleophiles, methylates hard ones, and epiminates alkenes.
V. F. Rudchenko, S. M. Ignatov and R. G. Kostyanovsky, J. Chem. Soc., Chem. Commun., 1990, 261 DOI: 10.1039/C39900000261
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