The behaviour of a new surface Rh dimer, prepared by attachment of trans-[{Rh(C5Me5)Me}2(µ-CH2)2] on SiO2 in three elementary reaction steps related to ethene hydroformylation, was observed by FTIR which revealed metal-assisted reversible insertion of adsorbed CO into an alkyl group, unlike Rh monomers.
K. Kitamura-Bando, K. Asakura, H. Arakawa, Y. Sugi, K. Isobe and Y. Iwasawa, J. Chem. Soc., Chem. Commun., 1990, 253 DOI: 10.1039/C39900000253
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...