The reaction of Os3(CO)12 with chlorine or bromine yields as the first observed product ax,eq-Os3(CO)12(X)2(X = Cl or Br) whereas the corresponding reaction with iodine gives [Os3(CO)12(I)][I3].
H. K. Sanati, A. Becalska, A. K. Ma and R. K. Pomeroy, J. Chem. Soc., Chem. Commun., 1990, 197 DOI: 10.1039/C39900000197
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